Effects of different penetration enhancers on pharmacokinetics of active components in Xiangfu Siwu transdermal patches Study on in vitro transdermal absorption properties of active fraction from Xiangfu Siwu Decoction Screening for differentially-expressed proteins in ovary of primary dysmenorrheal mice with Xiangfu Siwu decoction administration using nano LC-LTQ-Orbitrap-MS/MS