免费文献传递   相关文献

Preparation of Bamboo Activated Carbon by Different Parts of Bamboo and Their Adsorption on Phenol

不同部位竹材制备竹活性炭及其对苯酚的吸附性能


利用不同部位的竹材如竹蔸、竹节和竹枝制备竹炭,以KOH为活化剂,在活化温度为700 ℃和不同质量浓度的KOH溶液下进行活化制备竹活性炭,测定吸附性能最好的竹活性炭在不同吸附时间和溶液质量浓度下对苯酚的吸附情况,并进行结构表征。结果表明: KOH溶液质量浓度为16.0 g·L-1 时,制备的竹活性炭对苯酚的吸附效果最好,而竹蔸、竹节和竹枝活性炭中又以竹蔸活性炭吸附性能最好; 吸附时间在40 min时,竹蔸活性炭对苯酚的吸附趋于平衡,在30 ℃时竹蔸活性炭苯酚吸附量达到83.4 mg·g-1时趋向饱和。竹枝炭、竹节炭与竹篼炭的孔隙度分别为0.656,0.698和0.740,竹枝活性炭、竹节活性炭与竹篼活性炭的孔隙度分别为0.688,0.748和0.790。竹篼炭和竹篼活性炭比表面积分别为110.4和475.7 m2·g-1,孔容分别为0.09和0.26 mL·g-1,平均孔径分别为3.16和2.19 nm。

Bamboo carbons were prepared by bamboo butt,bamboo burl and bamboo branch,then the bamboo activated carbons were prepared by bamboo carbons at 700 ℃ under different concentration of KOH solution by using KOH as activator,the adsorption of bamboo activated carbon with best adsorption capability to phenol was measured at different time and solution concentration,and the structure of different carbon was also characterized. The results show that the bamboo activated carbon has best adsorption capability to phenol when the concentration of KOH solution is 16.0 g·L-1,and the bamboo butt activated carbon has best adsorption capability to phenol among the bamboo activated carbons prepared by butt,burl and branch respectively. The adsorption of bamboo butt activated carbon to phenol can reach to equilibrium when the adsorption time is within 40 min,and the adsorption capacity of bamboo butt activated carbon to phenol reaches to 83.4 mg·g-1 which tend to saturation at 30 ℃. The porosity rate of bamboo butt carbon,bamboo burl carbon and bamboo branch carbon is 0.656,0.698 and 0.740 respectively,and the porosity rate of bamboo butt activated carbon,bamboo burl activated carbon and bamboo branch activated carbon is 0.688,0.748 and 0.790 respectively. The specific surface area of bamboo butt carbon and bamboo butt activated carbon is 110.4 and 475.7 m2·g-1 respectively,and the pore volume is 0.09 and 0.26 mL·g-1 respectively,the average pore size is 3.16 and 2.19 nm respectively.


全 文 :! !"" ! !#
# $ $ %$ ! %
& ’ ( )
&’()*+(, &(-.,) &(*(’,)
./01!"**/1!
,234*
!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!
# $ $ %
#$s7mi0NmcnxOvIua7Q_ne
h‘i5 j k# Alm5 ^ff#
<51 =+&’(H))i’()xW()A ed !5$$$!a
#1 =+&’(H))X2xwU)A ed !5$$$!G
! "# K"#$s77mipm"NmF)m:0Nmx*6 678^c;7*bc;iH^ 9$$ :)#$(6
bH7 678,wzPQc;0Nmcnx*H[Q_ne+%7mcnxb#$Q_@&),w(6bHzI
ua7Q_jk*=PQT~V}STUVWX678,w(6bH^ 5;1$ <,-= 5@*0N7mcnxIua7Q_
KU+%*lm"NmF)m:cnx=}6m"cnxQ_ne+%aQ_@&b !$ >?@@*m"cnxIua
7Q_[$*+*b A$ :@m"cnxuaQ_68a BA1! ><,<= 5@[\^)Sm:xNmFxxm#x7p5
H0>^ $1;";*$1;%B) $19!$*m:cnxNmFcnxxm#cnx7p5H0>^ $1;BB*$19!B) $19%$Sm
#x)m#cnx9V/C0>^ 55$1!) !9"19 >#,<= 5*pM0>^ $1$%) $1#; >-,<= 5**Bp$0>^ A15;
) #15% @>S
$%&X mxamcnxauaaQ_a(&;LaT~V}
’()*+#+CA"51#9#ID59# ,-./0#, ,12+#5$$5 = 9!BB3#$$%4$! = $5$9 = $"
>?@#X#$$9 = 5$ = A$S
ABCDX(+EbOH[$CD<$;E5$$G*(+E(HHOaCD<#$$;F6A$BBGS
!"#$%"%&’() (* +%,-(( ./&’0% 2%"-() -3 4’**#"#)& !%"&5 (* +%,-((
%)1 67#’" .15("$&’() () !7#)(8
G?H@< D?@IJH@5 8J DJ@# -? D?H@<51 !"##$%$ "& ’()$*+(#, -.+$/.$ (/0 1/%+/$$*+/%*!$/)*(# -"2)3 4/+5$*,+)6 "& 7"*$,)*6 (/0 8$.3/"#"%6 !3(/%,3( !5$$$!a
#1 !"##$%$ "& 9$,"2*.$, (/0 1/5+*"/:$/)*!$/)*(# -"2)3 4/+5$*,+)6 "& 7"*$,)*6 (/0 8$.3/"#"%6 !3(/%,3( !5$$$!G
.-5&"%/&X EH>O// PH3O/@Q RS3S 23S2H3ST OI OH>O// OJUU*OH>O// OJ30 H@T OH>O// O3H@PL*ULS@ ULS OH>O// HPU?VHUST PH3O/@Q
RS3S 23S2H3ST OI OH>O// PH3O/@Q HU 9$$ : J@TS3 T?WWS3S@U P/@PS@U3HU?/@ /W 678 Q/0JU?/@ OI JQ?@< 678 HQ HPU?VHU/3*ULS
HTQ/32U?/@ /W OH>O// HPU?VHUST PH3O/@ R?UL OSQU HTQ/32U?/@ PH2HO?0?UI U/ 2LS@/0 RHQ >SHQJ3ST HU T?WWS3S@U U?>S H@T Q/0JU?/@
P/@PS@U3HU?/@*H@T ULS QU3JPUJ3S /W T?WWS3S@U PH3O/@ RHQ H0Q/ PLH3HPUS3?KST4 +LS 3SQJ0UQ QL/R ULHU ULS OH>O// HPU?VHUST PH3O/@ LHQ
OSQU HTQ/32U?/@ PH2HO?0?UI U/ 2LS@/0 RLS@ ULS P/@PS@U3HU?/@ /W 678 Q/0JU?/@ ?Q 5;1$ <,-= 5*H@T ULS OH>O// OJUU HPU?VHUST PH3O/@
LHQ OSQU HTQ/32U?/@ PH2HO?0?UI U/ 2LS@/0 H>/@< ULS OH>O// HPU?VHUST PH3O/@Q 23S2H3ST OI OJUU*OJ30 H@T O3H@PL 3SQ2SPU?VS0I 4 +LS
HTQ/32U?/@ /W OH>O// OJUU HPU?VHUST PH3O/@ U/ 2LS@/0 PH@ 3SHPL U/ SXJ?0?O3?J> RLS@ ULS HTQ/32U?/@ U?>S ?Q R?UL?@ !$ >?@*H@T ULS
HTQ/32U?/@ PH2HP?UI /W OH>O// OJUU HPU?VHUST PH3O/@ U/ 2LS@/0 3SHPLSQ U/ BA1! ><,<= 5 RL?PL US@T U/ QHUJ3HU?/@ HU A$ : 4 +LS
2/3/Q?UI 3HUS /W OH>O// OJUU PH3O/@*OH>O// OJ30 PH3O/@ H@T OH>O// O3H@PL PH3O/@ ?Q $1;";*$1;%B H@T $19!$ 3SQ2SPU?VS0I*H@T
ULS 2/3/Q?UI 3HUS /W OH>O// OJUU HPU?VHUST PH3O/@*OH>O// OJ30 HPU?VHUST PH3O/@ H@T OH>O// O3H@PL HPU?VHUST PH3O/@ ?Q $1;BB*
$19!B H@T $19%$ 3SQ2SPU?VS0I 4 +LS Q2SP?W?P QJ3WHPS H3SH /W OH>O// OJUU PH3O/@ H@T OH>O// OJUU HPU?VHUST PH3O/@ ?Q 55$1! H@T
!9"19 >#,<= 5 3SQ2SPU?VS0I*H@T ULS 2/3S V/0J>S ?Q $1$% H@T $1#; >-,<= 5 3SQ2SPU?VS0I*ULS HVS3H#15% @> 3SQ2SPU?VS0I 4
9#3 :("15X OH>O// PH3O/@aOH>O// HPU?VHUST PH3O/@a2LS@/0aHTQ/32U?/@a678aQU3JPUJ3S PLH3HPUS3?KHU?/@
m^c-N7s&X2*JK3my*5 #$$;/*YJm&/Cx # #$$ / L>#*$d
%mi 5 "$$/ Y # $$$/ U<.@d1*#$$#GSZ>
7miX2>^89*,uO=>my*!$$;/*)3m&/Cx 9#$/ L>#*!$mi
$V6x B$$ / Y %$$ / U*v=n*{~$x 5 $$$/ >A ci<#8L1*#$$#GS~
ymi%’7-SU}*%db)67miz;r*
pUK"vm^7dr(Hn1v0Nymx"!
Q_i’*_FxX2}K$wUNH#$$5a3|‘1*#$$5GSuacOn]5NTDl7
r(*U/awU=.7y>)7>?<’H3>/@H
!" #$ !*"##$G*R6K"mx7Q_neO6uaS
mipWz;rMN^m"NmFNm:1*_
@p’0Nmx@Jvc1k[P’2b_,S
0*B*vn
e5c#$7<@3W1*%&&’GS$@Dxmxb
>’7f%#‘*3\NJ=HWTm(Y%D&
0*(hmx7Q_ne*V}vd"yk*PeP
_qDPmxQ’7U}S^_?@#$s77m
i*8m"NmF)m:c0N7mx*J= ()*c
;s0N7mcnxIua7Q_ne*=IvP
Qbp5T~7V}S
" i’xCs
!"! N$K@/"O7
om<%&’$$()"#*&’) !+,$-)G<%&X(+’’$da(&;L<()*G*0Rvaua*0Rvas
r*0Rvamc(cnx*0Rv*z{VBgx’3pXfd
%7)E"x*"$I?"amax;(S
!"# 3PPZ7
B ’$d6kom*-)*1mi7 ’/#$s
7Xm"NmFNm:/+bCM=s< /$ 0*BF
4/b)*+=*/9hima(uY.?PQS
0*S0iH /1& 2*S0@& % 0*1M$kuvi
4BFS"J,#1S0%7mxPQDE=9*
>* "&& 3 %&&D<&+"/$ 3 &+&,- ..G&mx*E-*
N"S
!"$ 3PP(B
1S0%7m"xNmFxNm:x"(&;L
<()*Grc;7PQc;*Lw?B_[(67w
s7mxD/9-bG=*0>"#$(6WH7
()*,w)mxB02b4.e %/ 0*-w9^
" 4"&S1.e472bwzf4‘a7mx/9C
M=s<*)/9hima(=PQc;*c;iH
^ ,&& 2*Ni_[@&4|~ma(*1M$ku
vi4BFS1c;4‘a7mcnx"usr)
!"% 3PD3(.P!QRST.5"#
"+/+" %K&’z(=v h+(6bH^ %*/*
-*$*"& .5,67 "7ua,w*H[uaQ_:LE
!*b 1"& 8.4ez‘aQ_C(^X9:; < ." = *
> .&*/% < &+##% %*.& < &+"-,*." < &+/%$ /S
"+/+% <)5<89)C%KA*+WX Lw
?B_[6#$s77mcnxx_[(6bH7
ua,wb-bG=2b*B0>._[@&4*=
f‘/-,w*;,(6bH)!PQu.*b
1"& 8.4ezH[vQeH*;,k[ua:LE
!*R7/-,w(6bH*);,zwXcOTQ
_6xQ_SX
% <<0& = 1& 7 0& = 2 = 1"G?<0& = 1&G*
3 <2<1& 7 % = 1&G= 0&3?4S
c=X% ^Q_S*@a3 ^Q_6*.5,57 "a0& ^
p9ua,w7!C*.6a1& ^ua,w7pQ(
6bH*.5,67 "a1" ^Q_4H[7(6bH*
.5,67 "a2 ^u.{Aa4 ^mx"6*5S
!"& 3PD3(.Prs5u
"+1+" <)5<89),-.=v p5HVh
7p!=c3p57!CxF!C%9S^RC=
@"" AB#17GK*BzH.H[mx)mcn
x7p5HS
"+1+% <)5<89)Aht/0=v @"
9;9C %&"& 79V/C)pT~HR.
.DEFG.HIFDEJXfGH[^RC=0N7mx)mc
nx79V/CNpMxp$S
% TUxvu
#"! wxG>U_ ’()Vj!3(.PST.
5P$%
h+ %1& .5,67 "7ua,w*&+’ 5#$(6b
H ()*,wz0‘7ws7mcnxNWc;7m
x)c()E"xG/9-bG=*0>p9 "&& .6h
+%7ua,w*>. /& .D8B0Q_4fF/-
,w*u. 1&{4*"~]0eeH.H6z;u
a756*OT!&x7Q_SS()*,w(6b
HI#$s7mcnxQ_ne7/0*H[TU
XU "SxB+S ()*,w(6bHz0N7m
cnxxc;xOx9*XU %S
PU "*%R7*b#$(6bH7 ()*,wc
;>?z*~(6bH^ "-+& 5,67 "@*mcnxQ
_ne+%*(6bH# $+& 5,67 " R)a
"-+& 5,67 "@*mcnxQ_S~%R)*(6bH
8a %&+& 5,67 "@*mcnxQ_Sfl3cDm*
"cP$=77tbc;=0Sb_s0p5*D
mbmx7Q_neS#$s7mxbc;xxc
;47Q_ne3I)7’.*mxbc;47Q
_nei)$c;x*c;4Q_SB(hb ’&@
6k*()*,w(6bH^ "-+& 5,67 "@*m"cn
$&" & ’ ( ) /1"
U ! "#$,w(6bHImcnxQ_ua7/0
%&’( ! )**+,- .* -/+ ,.0,+0-12-&.0 .* "#$ 3.45-&.0 .0 -/+
263.17-&.0 -. 7/+0.4 89 82:8.. 2,-&;2-+6 ,218.0
U < {$s7mxxmcnx7uaQ_SI9
%&’( < =.:721&3.0 .* -/+ 263.17-&.0 12-+ -. 7/+0.4 89 82:8..
,218.0 206 82:8.. 2,-&;2-+6 ,218.0 *1.: 32:+ 721-
x7Q_ne{|$)E";*cn7bhizB0h|bx’s7IpT~*
R)bxV/C*#l(hbQ_neS
mi7#$s7=*m"0N7mx)mcn
x9v3 "s7bc"m^=7.H+)*T~+‘.*x3
{I]77IpnT~*p59V/C5+)*c6
Q_ne+%*mF0%*lm:7Q_ne]E*
2^m:u$m^&s*E0]7*.H|!*p5
T~#pm^zNs0U8S
!"! 3(.P!QRPST.5
<><>! *+[YC*+1UADE #k[R7*
b ?/#$s77mi0N7cnx=*m"cn
x7Q_ne+%*6zxBm1cnx^{^*?
@m"cnxb#$@&zIua7Q_jk*A
!Cs$x/Q_RCSua,w(6bHB^
!@@ :’,AB !*!C^ !@@ :A*m"cnx)x(6B^ @>? ’*b ?@ C)n*0>&c_[@&
B{H[,w=z;ua7(6bH*Q_@&I
mcnxQ_ua7/0TUpU ?chS
U ? @&ImcnxQ_ua7/0
%&’( ? )**+,- .* -&:+ .0 -/+ 263.17-&.0 -. 7/+0.4
89 82:8.. 2,-&;2-+6 ,218.0
B!B m"cnx D2:8.. 85-- 2,-&;2-+6 ,218.0*B"B =.::+1&,24 2,-&;2-+6 ,218.0( z$ E/+ 32:+ 8+4.F(
PU ?R7*x ?@ :&0’m"cnxxnx7Q_S^-SkY7|m*?@ :&0 4*Q_S
:;#)*x*$Q_@&xyb ?@ G H@ :&0]b<><>< GZ2.3.C*+1UADE 0>h
+(6bH^ !@*<@*I@*!@@*<@@*I@@ :’,AB !7ua,w*Lw?B "#$,w(6b
H^ !J>@ ’,AB !@0N7m"cnx)w @>? ’+$-bG=*p9h+%7,w !@@ :A*
b ?@ C)nz>. H@ :&04fF,w*"~]0e
eH.H[vz;,w(6bH*OTQ_6xSS
,w(6bHIm"cnxIua7Q_S7/0
pU Hch*,w(6bHxm"cnxQ_ua
7Q_67|tpU IchS
PU H*IR7*~,w(6bHR)@*Q_S
zD*(6bH)$ !@@ :’,AB !4*Q_SzDW
G*"~yQ_S7zD*Q_60\R)*(6b
Ha8 ?@@ :’,AB !4*A^8aQ_*+*m"cn
x7Q_68a K?>H :’,’B !)n@[\^)S
L@!! H# ]VS1X#$s7mi0NmcnxOvIua7Q_ne
U ! ,w(6bHIm"cnxQ_
ua7Q_S7/0
"#$% ! &’’()* +’ ,+-.*#+/ )+/)(/*01*#+/ +/ *2( 13,+04*#+/
01*( *+ 42(/+- 56 5175++ 5.** 1)*#81*(3 )105+/
U 9 ,w(6bHIm"cnx
Q_ua7Q_67/0
"#$% 9 &’’()* +’ ,+-.*#+/ )+/)(/*01*#+/ +/ *2( 13,+04*#+/
)141)#*6 *+ 42(/+- 56 5175++ 5.** 1)*#81*(3 )105+/
!"# 3PD3(.Prs5u
:;<;= <)5<89)A,-. p5H7)!
cmx)mcnx’sT~7_C-NQ:*bQ
_r(=*p5HIvQ_ne3I-N7/0*^
RC0N7mxxmcnx7p5H:*TUpV
=chS
PV =R7*#$s77miS0F7mx7
p5H_b_[’>*mxWc;x*m:x7p5
H^ >;?9?*mFx7^ >;?@A*m#x7^ >;B!>*
v=m#x7p5H+)*m:x7+!*"MNc
P$miK/#$7s7%%.H#$7y7*c
6m#x7Q_neN%$v3s77mxS#$s77mi0N7mxc;4*p5H;3_
[7Rp*tsm:cnx7p5H^ >;?AA*mF
cnx7^ >;B!A*m#cnx7^ >;B@>*v=m
#cnx7p5H]M+)SwWc;77!")
]h7iHP_qQBbmx’s7pT~*R5
bmx7Q_neS
5 $ 3P@3(.PP{W_
%&’($ )*+*,-./ +&.0 *1 ’&2’** 3&+’*4
&45 ’&2’** &3.-6&.05 3&+’*4
s7 C+,#*#+/
m:
D175++ 501/)2
mF
D175++ 5.0-
m#
D175++ 5.**
mx D175++ )105+/ >;?9? >;?@A >;B!>
EFGc;mcnx
D175++ 1)*#81*(3 )105+/ >;?AA >;B!A >;B@>
:;<;: <)5<89)Aht/0 ^RCc0
N7mx)mcnx79V/C)!)pT~HR
TUpV :chS
5 ! 3P@3(.PP=5X$
%&’(! 7803-1-3 ,9+1&30 &+0& *1 ’&2’** 3&+’*4
&45 ’&2’** &3.-6&.05 3&+’*4
c;x4
D(’+0( 1/3
1’*(0 1)*#81*(3
Q: H/3(I
9V/C
J4()#’#) ,.0’1)(
10(1K<7:,$L =G
pMC
C+0( 8+-.7(K
<7M,$L =G
p$
C+0( ,#N(K/7
m#x
D175++ 5.** )105+/ ==>;! >;>@ <=;?
EFGc;m
#cnx D175++ 5.**
1)*#81*(3 )105+/
!B9;B >;:? :=;@
P V : R 7*m # x 7 9 V / C ^
==>;! 7:,$L =*U EFGsc;49V/Rpa !B9;B
7:,$L =*9V/C3])ReaU EFGc;47m
#cnxpM59m#xR)bI7*m#x^
>;>@ 7M,$L =*U EFG c;7m#cnxpM^
>;:? 7M,$L =am#x7*Bp$)!b <;=? /7*U
= EFGsc;4*m#x=3$77uIp5dh
|*m#cnx7*Bp$^ :;=@ /7Smxc;
4*9V/C3])Re*uIp5R7*#lKm
cnx7Q_ne3R)S
< Tu
=GPm"NmF)m:1 <"#$s7mip
Wz;r0N7mxxmcnx*Q_neB#$*
v=6m"0N7mx)mcnx7Q_ne+
%S@" EFGsPQc;*EFG,w(6bH^
=?;> $,ML =@*c0N7mcnxQ_ne+%S
mcnxQ_ua7e.{|nxQ_ua7Q_@&xy <> O !> 7#/*m"c
nxIua7Q_68a A<;! 7$,$L =)n@[^)S
>== & ’ ( ) !9"
!G#$s77miS0F7mx7p5H_
b_[7’>*m:xNmFxxm#x7p5H0
>^ "#$%$*"#$&’) "#()"*U= *+,c;4*m:
cnxNmFcnxxm#cnx7p5H0>^
"#$’’*"#()’ ) "#(&"Sm # x 9 V / C ^
--"#) .!,/0 -*U *+,sc;4m#cnx9V/
C R p a )(%#( .! , /0 -a m # x p M ^
"#"& .1,/0 -*U *+,c;47m#cnxpM^
"#!$ .1,/0 -Sm#x7*Bp$)!^ 2#-$ 3.*
U *+,sc;47m#cnx=3$77uIp
5dh|*m#cnx7*Bp$^ !#-& 3.S
E F , -
R[z*~ _ 4 !""- 4 mx7S0)"Z|U 4 m^?@?9*!"
#8L*.@d 4 !""! 4 mxi’73Kd"’uO?@P} 4 tl
&’)))4*2"<)GX%2 0 %$4
@3W*2td*"-* 4 !""2 4 min(OvX2|UK"7?@
P} 4 tl&’)))4*2-<%GX(- 0 ((4
3|‘*._:*~_+ 4 !""- 4 mx7S0W%x’;ne|tp
+ 4 m^?@?9*!"<2GX)) 0 )’4
.@d*#8L 4 !""! 4 -Umi;)K"*|Umxd"HW 4 +
/&’)))4*!$<-GX- 0 )4
567.836 9*:;<=6;> ?4 -&&’ 4 @AA;BC 8A D;3>ECF A 83 C=; H=F>EB6<
H78H;7CE;> 8A 6 DE>87D;7;D B67I834 J8G736< A87 KHHEB>*)&$"% 0 $2&4
!"#$% #;$)
---! )# ]VS1X#$s7mi0NmcnxOvIua7Q_ne