Two new sterols, 3β,7α,16β-trihydroxy-stigmast-5,22-diene (1), 3β,7α,16β-trihydroxy-stigmast-5-ene (2), were isolated together with six known compounds, ergosta-5,24(28)-dien-3β,7α-diol (3), ergosta-5,24(28)-dien-3β,7β,16β-triol (4), β-amyrone (5), β-amyrin (6), 11α,12α-epoxy-14-taraxeren-3-one (7), and 6-guaiene-4α,10α-diol (8) from the EtOH extract of the bark of Amoora yunnanensis (H. L. Li) C. Y. Wu. Their structures were deduced on the basis of spectral data.
云南崖摩的化学成分研究
罗晓东 吴少华 马云保 吴大刚*
(中国科学院昆明植物研究所植物化学开放实验室,昆明650204)
摘要: 从云南崖摩(Amoora yunnanensis (H.L.Li)C.Y.Wu.)树皮的乙醇提取物中分离得到8个化合物,通过波谱方法鉴定它们分别是:3β,7α,16β-trihydroxy-stigmast-5,22-diene(1)、3β,7α,16β-trihydroxy-stigmast-5-ene(2)、ergosta-5,24(28)-dien-3β,7α-diol(3)、ergosta-5,24(28)-dien-3β,7β,16β-triol(4)、β-amyrone(5)、β-amyrin(6)、11α,12α-epoxy-14-taraxeren-3-one(7)和6-guaiene-4α,10α-diol(8)。其中1和2为新化合物。
关键词: 云南崖摩;楝科;3β,7α,16β-trihydroxy-stigmast-5,22-diene;3β,7α,16β-trihydroxy-stigmast-5-ene
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