摘 要 :从屏边三七(Panax stipuleanatus Tsai et Feng)根茎中分离到二个齐墩果烷型新皂甙,命名为屏边三七甙(stipuleanoside)R1和R2,其化学结构经光谱分析和化学降解反应,分别确定为齐墩果酸-3-0-β-D-葡萄吡喃糖基(1→3)(α-L-阿拉伯呋喃糖基(l→4)-β-D-葡萄吡喃糖醛酸甙(1)和齐墩果酸[28-O-β-D-葡萄吡喃糖基]-3-O-β-D-葡萄毗哺糖基(1→3)[α-L-阿拉伯呋喃糖基(1→4)]-β-D-葡萄吡喃糖醛酸甙(3)。
Abstract:The two new oleanolic acid-type saponins were isolated from the rhizomes of Panax stipuleanatus Tsai et Feng whose chemical structure were elucidated to be oleanolic acid- 3-O-β-D-glucopyranosyl (1→ 3 ) [α-L-ara- binofuranosyl (1→ 4 )]-β-D-glucuronopyranoside (1 ) and oleanolic acid-[28 -O-β-D-glucopyranosyl]- 3-O-β-D-glucopyranosyl (1→ 3 ) [α-L-arabinofu- ranosyl (1→ 4 )]-β-D-glucuronopyranoside (3 ) and were named stipuleano- side R1 and stipuleanoside R2, respectively.