免费文献传递   相关文献

Study on triterpenes from Solanum torvum

金钮扣中三萜类化学成分研究



全 文 :t“”rƒ¨\]Ú6ƒ„
4)¨
P
#
.`
W
#
›óœ
P
!
!Pg
êãK¯J8&12
#
êã 8&
LWN^LN%
Wg
êãK¯J 8K¯J
#
êã êV
LPMMMX
$
„;
%!

&
At“”r[ƒ¨\]Ú6EɃ„

žŸ
.

_Lh
íÖµ#
!
\›P¥
#1(U#$5(KB.;WM
‡¸{–”
EÉ6g
!
›
><3
Ñ
<1
6‹/Ô\ÄÌ01

 ¡
.
±t“”
_Lh
íÖµ#Ì[Fò4#ØIr6g&ì
X
ƒ\Ä
Ì
!
6îê
O

;
íîs©Ù•@
$!%#O

;
íîœs
;PP
#
!PW
#
;

;
©Ù•Q
;WN!PO

;
~u
$#%#
©Ù•@
$$%#
®•@
$%%#W
#
;
j
s©Ù•@
$&%# W
#
!O

;
üjs—a@
$%
 t
.
\ÄÌ
! `
Œêp5±‰ÉÌr&ì

$
…†‡
%!
ºö
&

&
t“”
&
ƒ
$
8ˆ$f
%!WMPMPPWOMMO
$
–—Eq
%!
ržSÎýRôrÇ­
$
é,Çä5sQ
%
«u
Fstuv
$WMM[9WMM[%
$
‰‚>Š
%!
!
¤¤»
!
 kn
!
ÎÏã½w
!
‚&±×rÇY·
#
™
¬ƒ„
!@(&.$M[XM%NNWM[__N!-;I$&.H$)PO_\2/IgG/I
!!
t“”êºöº¹ÉÌpº
$&/0,26!&5>26
[
NÐtGê

6Æ6ª¼ýQ(
!
w貪
!
m
Ë
!

!
Ý?
!
ÝdgÞé
!
6úRrÇÁÀ+H%
êQ…v›ÇÁ
P(

7«1(±‰ÉÌr6g[
\]Ú6èÕþ¨
#
@A¨Ñè¯@

ê&ÚªÍ
›ÌYs©
!
¤ƒ„At“”Q_Ø6[\]Ú6
EÉ%ƒ„
!
Ð6g&ì%
X
ƒ¨Ú6
!
ΐp
5±‰ÉÌr6g&ì

!
ßàiÁÂ
+;^
uXÜ-%Ôß
$
u.¡Å»
%&7%4V(%
=S=>-
+
LMM <.`
 ½*ûÐü–ß
&@#(%I/
R1e-:;I$000U(G2%/I(2(%
Y–ß
&74G#1(U$G/%(
r
?MÜÝ{–ß

¸{–›P¥
$WMM iOMM
v
%#
¸
{–›P¥
$OMM i^ MM
v
%#
Q4{–›P¥
$
ΐ
ðù&ú\Nåäö
%!1(U#$5(KB.;WM$8#$%I$G$
–$äö
%
²›çیê6‹.

öêt“”Q_Ø6
!WMMN
÷
N
²ÿl6)
R;¤S
!
Ë6úÇ]4ǛÉÌkƒð¤¤» 
knÕÔêºöÉÌpº
$g!&5>26
¤Œ6
úÇ]4ržÅ(§¨rß

#
µ#i6g
#NÐt“”Q_Ø6ðÃ
WM V*!
a
_Lh
íÖ
WMM B
Èqµ#
W #!
Ð
O
5

¥¡
!
³MÈHíÖ
!
&^â;
PgN V*
#^âŽ%pr
!
¦5›F
ò
#
èø
#
í@íu
#
»íÖ4#
!
4#_³M<¢&
Fò4#Ì
W^L *
#Fò4#Ì
WMM *!
aF
òsm
!
P¥K’bN¾
!
P¥{–¸6g
!

ò
;
í@íu
$LMqP i
í@íu
%
bõ›
!
Q4{–
-¨Ä>jZõ›q6
!
Ð&ì
O
q6
J%gP i
J%gO!J%gP
_
74G#1(U$G/%(
r?MÜÝ{–ß
$
¸
{–›P¥
!OMM i^ MM
v
%!
Fò
;
í@íu
$PLq
P%
õ›
!
֏
1(U#$5(KB.;WM$
èø
;
‚Ö
PqP%
ª¥
¸{–.\¾
!
èø
;
‚Ö}ji0×&\ÄÌ
!
$PPL I*%!
\ÄÌ
#$O[ I*%&J%gW
_
74G#1(U$G/%(
r?MÜÝ{–ß
$
¸{–›P¥
!OMM i^ MM
v
%!
èø
;
‚Ö
$WMqP%
õ›
!
֏
1(U#$5(KB.;WM$
èø
;
‚Ö
PqP%
ª¥¸{–.!
&\ÄÌ
$$LW I*%!
ÄÌ
%$N I*%&J%gO
Ë
74G#1(U$G/%(
r?MÜÝ{
–ß
$
¸{–›P¥
OMM i^ MM
v
%!
*ÅQ
;

$LqP%
õ›
!
֏
1(U#$5(KB.;WM$
èø
;
‚Ö
PqP%
ª¥¸{–.!
\ÄÌ
&$PM I*%!
\ÄÌ
$_ I*%
$
01ÕÔ
\ÄÌ
!
t{±×
$
èø
;
‚Ö
%!
4sè
ø
!IU W^X iW^N r!B(b(%I$)) ;74%G#$%5
}\4
›
-:;<1 6 VI^ _N $<
u/
%!
P
.;><3 $R&
O
!
LMM <.` %
!
. Mg[L! MgNL! MgN[! Mg_P! Mg_O! Mg_^!
PgPO!$($G# O .!0![ n.
O
%!WgM^ $O .!0!T=G%!
WgNW$P .!55!GYPLgM!OgW .`!.;PN%!^g^_$P .!2!
GYNgM .`!.;O%!LgW[$P .!2!GYWgL .`!.;PW%
PO
;><3$R&
O
! PWL <.` %
()9¹Y¼
P
i7
«
W(
A“s¤|Ç
!
/Ô\ÄÌ
!
ê
O

;
íîs©
/X_MW/
{
OX
ï{
PL
•
WMPP
÷
N
²
!!!!!! ! ! ! ! ! !!!! ! ! ! !
S/&gOX! :004(!PL
=4*402! WMPP
ٕ@
$O

;$G(2A&/&($)/&G$G5%
¼
P!
\ÄÌ
! `
[
PO
;><3$LMM <.`%
()
>/g ! # $ % &
P ONgP O[gN ONg^ O[g^ ^XgM ^XgO
W WWg_ WOgP W[gW WXg^ XXgN XXgN
O NMg_ NMg^ [_gM [NgO NWgP NWgP
^ O[g[ O[gN ONg[ O[g[ ONgP O[gN
L LLgO L^gX LLgW LLg_ L^gW L^gW
X PNgW P[g^ PNgO P[gP P[gP P[gP
[ OOgN OPgM OWgX OPgN OPgL OPgN
N O_gO ^PgO O_gO ONgW ONgP ONgP
_ ^[gX LMgX ^[gX ^NgW ^Xg^ ^XgO
PM O[gM OXg^ O[gP OLgX OXgN OXg[
PP WOg^ LWgX WWg_ WPg_ WWgM WWgM
PW PWWgX L[gM PWWgX PWLgN PWMg[ PWOgN
PO P^OgX N[gL P^OgX PO[gL P^OgP PO[gX
P^ ^Mg_ ^MgL ^PgX ^MgN ^MgL ^MgN
PL OWgL W[gM W[g[ W[gM WXgL WXg_
PX WOgX WPgO WOg^ WOgW WWgW WOgW
P[ ^XgL ^OgN ^XgL ^XgO ^^g_ ^XgO
PN ^PgX ^_gX ^PgM LOg[ ^MgW LPgN
P_ ^LgN O[g[ ^LgN O[gN ^^g[ ONgO
WM OMg[ OPg^ OMg[ O[g[ W_gW O[g[
WP OWg^ O^gO OOgN W_g^ OWgL W_gO
WW W[g[ WXg[ OWg^ OLg[ OPg^ OLg[
WO WNgM W[g[ WNgP W[gP W[gX W[gX
W^ PXgX PXgW PLgL P^g_ PLg_ PLgN
WL PLg^ P[gW PLgO P^gM PLgP PXgM
WX P[gW WMgM P[gP PLg[ PLg[ PLgW
W[ WLg_ PNgN WLg_ WWgW W^g^ WWgW
WN PNWg_ P[_gO PNOg^ P[NgW P[Ng^ P[NgW
W_ OOgM OOgW OOgM PLgN OPgL PLg[
OM WOgL WOgX WOgX P_g[ WW P_g[
OP WPgO WPgO
OW P[PgM P[Mg_
!!
?
.
\ÄÌ
! $`
[sÛê
R&
O
!
\ÄÌ
% `
[sÛê

L
R
L
>
\ÄÌ
#
t{±×
$
èø
;
‚Ö
%IU sOMM r!
-:;<1 6VILPW $<
u/
%!B(b(%I$));74%G#$%5
}4›

P
.;><3$R&
O
! LMM <.` %
!
. MgN[! MgN[!
Mg_W!PgMM!PgML!PgM[!PgPM$($G# O .!0![ n.
O
%!
WgMX$O .!0!;T=G%!WgOP$P .!55!GYP^gM!OgL .`!
.;PN%!OgMP$P .!55!GY^ gM!PgL .`! .;PP%!OgMO
$P .!5!GY^gM .`! .;PW%!^gLO$P .!55!GYPPgM!
LgL .`! .;O%
PO
;><3$R&
O
!PWL <.` %
()9
¹Y¼
P
i7«
O(
A“s¤|Ç
!
/Ô\ÄÌ
W
ê
O

;
íîœs
;PP
#
!PW
#
;

;
©Ù•Q
;WN!PO

;
~
u
$ O;F;=G(2A&;PP
#
! PW
#
;(U/KA;/&($)$);WN! PO

;/&;
5(%
\ÄÌ
$
t{ÃÁ
$
èø
%!
4sèø
!IU
W_X iW_N r!B(b(%I$));74%G#$%5
}\4›
-:;
<1 6VI^ LX $<
u/
%!
P
.;><3$R&
O
!LMM <.` %
!
.Mg[L!Mg[[!Mg_M!Mg_P!Mg_O!Mg_N!PgPO $($G# O
.!0![ n.
O
%!OgWM$P .!55!GY^ gN!PPgW .`!.;
O%!LgW[$P .!2!GY^ gW .`!.;PW%!WgNW$P .!2!GY
^gL .`!.;PN%
PO
;><3$R&
O
!PWL <.` %
()9
¹Y¼
P
i7«
^(
A“s¤|Ç
!
/Ô\ÄÌ
$
ê©Ù•@
$/&($)/&G$G5%
\ÄÌ
%
t{ÃÁ
$
‚Ö
%!
4sèø
!IU
W[L iW[[ r!B(b(%I$));74%G#$%5
}\4›
-:;
<1 6VI^LX $<
u/
%!
P
.;><3$
L
R
L
>!LMM <.`%
!
.MgN_!Mg_L!Mg_X!Mg_N!PgMM!PgMP!PgML $($G# O
.!0![ n.
O
%!Og^X$P .!2!GY[g_ .`!.;O%!Lg^_
$P .!2!GY^ gP .`!.;PW%
PO
;><3$
L
R
L
>!PWL
<.`%
()9¹Y¼
P
i7«
L(
A“s¤|Ç
!
/Ô\ÄÌ
%
ꮕ@
$4%0/&G$G5%
\ÄÌ
&
t{ÃÁ
$
Fò
;
í@íu
%!IU
W^L iW^[ r!B(b(%I$)) ;74%G#$%5
}\4›
-:;
<1 6VI^[W $<
u/
%!
P
.;><3$LMM <.`!
L
R
L
>%
!
.Mg_^!Mg_N!PgMM!PgMW!PgMN!PgWX!PgWN $($G# O
.!0![ n.
O
%!OgW_$P .!55!GY^ gX!PPgL .`!.;
PN%!OgO_$P .!5!GY_gO!.;O%!^gPM$P .!25!GY
^gW!PPgW .` !.;W%!Lg^[$P .!b%0!.;PW%
PO
;><3
$PWL <.`!
L
R
L
>%
()9¹Y¼
P
i7«
X(
A
“s¤|Ç
!
/Ô\ÄÌ
&
ê
W
#
@
js©Ù•@
$W
#
;#A5%/KA/&($)/&G$G5%
\ÄÌ

t{ÃÁ
$
Fò
;
í@íu
%!IU
W^W iW^^ r!B(b(%I$)) ;74%G#$%5
}\4›
-:;
<1 6VI^[W $<
u/
%!
P
.;><3$
L
R
L
>!LMM <.`%
!
.Mg_^!Mg_L!Mg_N!Mg__!PgM^!PgWM!PgW[ $($G# O
.!0![ n.
O
%! ^gPM $P .!I!.;W%!Og^M $P.!5!
GY_gL .`!.;O%! WgXW$P .!5!GYPPgL .`! .;PN%!
Lg^X$P .!b%0!.;PW%
PO
;><3$
L
R
L
>!PWL <.` %
()9¹Y¼
P
i7«
[(
A“s¤|Ç
!
/ÔÄÌ

ê
W
#
!O

;
üjs—a@
$W
#
!O

;#A5%/KA4%0/&;
G$G5%
$
‹ŒŽ
%
P(!
6úRqöÇö͘ڥ2
g
6úRrÇÁÀ+
g
{
P
^
1(g

.
6úö÷KÂg
!WMM^.POXg
W(!
tÖv
!
Æ­™
!
\ç½
!
‡
g
í-K[\]Ú6ƒ„
9(g
r
/[_MW/
{
OX
ï{
PL
•
WMPP
÷
N
²
!!!!!! ! ! ! ! ! !!!! ! ! ! !
S/&gOX! :004(!PL
=4*402! WMPP
­ÇÌ\]£¤
!WMM[!P[$X%.O_Mg
O(!9/0(<$)4(&! >$%D$(`<$02$G#(! &$45$1/2/! (2$&g=)2/K5$)2
(D$&4$2/) /6C7)-,+05.!(0 0U(G(0$J$b$G($(%. %($&A0A)2#(00/6
O;F;$G(2A&;PP
0
!PW
0
;(U/KA;/&($)$);WN!PO

;/&5(0/&$2(5 6%/ICg
/0!7*050 $)5 20U%/2(G2D((6(G2) (KU(%I()2$&5$b(2(09(F
7/&8#$%I74&!WMM[!OM$N%.PLMOg
^(!
F´9
!
Fx¶
F
¸ä‰b[\]Ú6ƒ„
9(g
8éäÌ
ƒ„i—
!WMM_!^M$P%.W^g
L(!
/¾Ž
!
L\Ž
!
/ÏØ
!
‡
g
H¿h\]Ú6[ƒ„
9(g
r
­Ç]£¤
!WMM_!^^$P%.P_g
X(!
£.
!
Ɠµ
!
$öl
!
‡
g
rÎÀÁÛê[\]Ú6ƒ„
9(g
r­rÇ£¤
!WMM[!OW$PX%.PXXOg
[(!
$(
!
éµ
!
Â!“
!
‡
g
åx•§\]Ú6[ƒ„
9(g

rÇ£¤
!WMMW!W[$N%.L_Xg
=DIHF BCDG0DAGNACAKMGB.9&(-.4$&%#.4
d.T,./)*b/
P
! a=>?J()*
W
! J=>?d#H$)
P
!
$PgH20,;.&,; <+0560*-2!(*0/=,(>-5)(!7W+&,;)+0, %062)! W+&,;)+0, LWN^LN! %+(,0&
Wg$*+&&/&3850.(!(&,0/%+(,-)-4-.(*(,-! H20,;.&,; <+0560*-2!(*0/=,(>-5)(!7! H20,;I+&2 LPMMMX! %+(,0%
6OKDG/UD(8O\AUD0SA. @/0245A/) 2#(G#(IG$&G/)0224()20/6$&/0,26!&5>26g>ADEBH. @#($(%$&U$%20/6$M!&5>260E$%;
2`E(%((K2%$G2(5 E2# _Lh $&G/#/&$)5 2#(G/)0224()20E(%(0/&$2(5 $)5 U4%6(5 bAG#%/I$2/*%$U#G0&G$*(&$)5 1(U#$5(KB.;WMg
@#(%02%4G24%(0E(%(5(2(%I)(5 bA><3$)5 <1 0U(G2%$&$)$&A00g:AKI1D. 1K2%2(%U()(0E(%(0/&$2(5 $)5 5()26(5 $0O

;
$G(2A&/&($)/&G$G5$!%!O;F;$G(2A&;PP
#
! PW
#
;(U/KA;/&($)$);WN! PO

;/&5($#%! /&($)/&G$G5$$%! 4%0/&G$G5$%%! W
#
;#A5%/KA;
/&($)/&G$G5 $&%! W
#
! O

;5#A5%/KA4%0/&G$G5 $%g2BCU1IK0BC. =&G/IU/4)50E(%(/b2$)(5 6%/I2#0U&$)26/%2#(6%022I(g
A^F VBGHK(!1/&$)$G($(& $&/0,26!&5>26& $4&0(23$5K1/&$)@/%D& 2%2(%U()(0
HB0.!+_%#)RU\U..#+!!!&!)
$
$Q
!
¥Z¦
%
/N_MW/
{
OX
ï{
PL
•
WMPP
÷
N
²
!!!!!! ! ! ! ! ! !!!! ! ! ! !
S/&gOX! :004(!PL
=4*402! WMPP