免费文献传递   相关文献

Chemical Constituents of Volatile from Pine Needles of Pinus yunnanensis

云南松松针的挥发性化学成分*


The volatile from pine needles of Pinus yunnanensis was extracted by steam distillation. The chemical constituents of the volatile were analyzed by GC-MS and their rative contents was determined by area normalization. 53 compounds were separated, 50 of them were identified.These 50 compounds amounted totally to about 94% of the components in the volatile and 97.467% of the total peak area. The maior components of the volatile were palmitamide(16.581%)and germacrene D(15.045%).


全 文 :! !"" ! "#
# $ $ %$ " %
& ’ ( )
&’()*+(, &(-.,) &(*(’,)
./01!"**/1"
234*
!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!
# $ $ %
|#dd6;X|d!t@)"
% p5 %qr5 %s55 Ztb# Du<6 jAb!
E51 BaqAa’W’3RSTUV BaH)*’GH> BF ""$$#"W#1 Ba\3&W’3wm>^L BF ""$$$5W
61 BFPN)v BF ""$$$6W!1 Ba\&’()GHv3&P9GH> BF ""$$$5d
$%&a ,CIWI|WkxiW})sC
’()*+#&75817 -./01#, -23+#5$$5 9 7!884#$$%5$" 9 $576 9 $"
TUV#a#$$8 9 $% 9 $#M
3WXYaXY&’f$%!8’XYE#$$:;!;!$dWPNQB./‘a0]J4/lE*’)+;$7;$##5dhJXYM
"->x)lmAgMBa\vX()vR[zi})RSTUV(I7HrOJ|} <’;2&CD*Sm9RtGM
!"#$%&’( !)*+,%,-#*,+ ). /)(’,%(# .0)$ 1%*# 2##3(#+ ). !"#$% &$##’#(#%"%
=3>? =3>5 =3>? 23/@35 =3>? A3BCD35 ED3>? FB4/>?# G3>? ’C3/4B>?6 =D FB>4/>?!
E5 H !"#$%&" ’() *+,&-+.&-) /&- 01+2. 0(3. 4+2+5(6(2. &/ 4&"2.+#2&"3 7(5#&2 823.#.".( &/ 92.&6&1&5)*!"#$%&" :2#;(-3#.) !"#)+25 ""$$#"W
# H <%( =&-(3. 0(3. >"+-+2.#2( ?&2.-&1 @.+.#&2 &/ !"#$%&" 0-&;#2A( !"#)+25 ""$$$5W6H !"#$%&" 9B"A+.#&2 ?&11(5( !"#)+25 ""$$$6W
! H 823.#.".( &/ =&-(3. 0-&.(A.#&2*!"#$%&" CA+B(6) &/ =&-(3.-) !"#)+25 ""$$$5d
45+,0’&,a +CI J/03KB0I @L/M NB>I >IIO0IP /@ 0#2"3 )"22+2(23#3 Q3P IRKL3SKIO T4 PKI3M OBPKB003KB/>H +CI SCIMBS30 S/>PKBKDI>KP /@
KCI J/03KB0I QILI 3>304UIO T4 <’;2& 3>O KCIBL L3KBJI S/>KI>KP Q3P OIKILMB>IO T4 3LI3 >/LM30BU3KB/>H "6 S/MN/D>OP QILI PIN3L3KIO*
"$ /@ KCIM QILI BOI>KB@BIOH+CIPI "$ S/MN/D>OP 3M/D>KIO K/K3004 K/ 3T/DK %!V /@ KCI S/MN/>I>KP B> KCI J/03KB0I 3>O %71!:7V /@
KCI K/K30 NI3W 3LI3H +CI M3B/L S/MN/>I>KP /@ KCI J/03KB0I QILI N30MBK3MBOIE5:1"85Vd3>O ?ILM3SLI>I XE5"1$!"VdH
6#7 8)03+a 0#2"3 )"22+2(23#3WNB>I >IIO0IPWJ/03KB0IWSCIMBS30 S/MN/PBKB/>P
,CIE0#2"3 )"22+2(23#3d*"e|W!IMC
1(6+SCQ8,C8S=RCQ8.SSQ8Ba
SQ*4P@) :$$ Y # 5$$ M5.HA.*"jsH
5Cf&LA\DTOes{y&Mn$o*,C
I&5P9‘js)3&hKjcQP;\64x
xN5RFi&GIM,CI%ITOD‘6DE
A2xO‘J*’5_,A63*\v9oB3’
,CI\kE0#33&B(3 )"22+2(23#3dr/XSCA.,
C8Ba86+eA,CI&.5635ClC1.
/)$CH*,<>)35z{M%I3’5>^
89&rFHEtzqe*#$$!d*|r\)3Y-n
F!Kg0Z"Pp#1})+{lhi+{o|
}>^*’\]jk8,(8Yy5>^\]M_i
St"5hPLAB*-zh{Z0H,O’OJ
5kxBiu*%&iujsO_ijROJ5n
u*"):*’5UnA<8z|8~D8_,e@O
})*K*’S:0Un5$L$[v*Un_iZ
05kxBphiuB:O:5lm4@AgES
/He*#$$8dMSBa%IAP<=B*,CIk563xh*0A,\O95q4M,CIkx
BOPeC6f!,CI\krUnA<*+5R
FjkiM
cf,CII|kxBiu!,$I&&O5
GHHI*[O\GHC15,CI*#$9%,C\=*=z.5,C
II|kxBjReC‘JbnPQoEx11e*
5%87W2RRe*#$$#dMBaA.,CII|kx
i5GHir#HIM1(JI*O_i*DBk
xi5+i-9:n~lWy|}‘J54M*h
z<=LKW^k‘J*\kxB})sC5es
sCl+iZ-,QonPElBhe*#$$!WWi
Je*5%%"dMPGHoprBaA.,CII|k
xB})sC|}GHHI*KgE?j?!nl
j&XY 9uY 9/H#-g\]*rBaA.,
CII|kxi|}M_8CwA@A*rsWXO
5#%zcfs,CII|kxinFsC*z#f
)|Is8RBaA.,CI\kA,CI5Uh
*+#~*)B#/N,CIkxin~BZ05
68,CI\kWRJy ),HMN&O5PQ3nM
B ! ,CII|kxi(w-5B
"#$% ! &’( )*)+, #*- .’/*0+)*$/+0 *1 2*,+)#,( 1/*0 3#-( -((4,(5 *1 !"#$% &$##’#(#%"%
! 89I+R
!6! ?@ 7889$ !7%(Ba\8WbaE]K
WTy) 9$5,CI 7$h}A*gN61L3
o4*4’HE55vEq*~DTUVNzM
!67 }~ :;!87<8=tJB4""’ERi]6(\xN,8:;d8>=:?t"]JhCEFG
v<:’n’,8:;d8:@gnE\XQH:;d8&IJK887tJ-R7EFG7
@fTn’c.,8:;dM
!6E op !dE?j?!>_nM_I|T _B
wcfNz_iKr !88 $*n~B0x! 888 0L5
?!wv*< K88 0L?!E*E?j?! K ’M!C
g{8>_*mEW?-Z) 7K ’M_ !!LM_5
I|T|}uYCDM
7dM_i FGJH;c.w~ I|M_iCD
~zS :@i) ! MLMFGAqaXYi) NIJOP*Q+REE868 0 S
7D8!0 S 867D!0d.BDt+ZQi*i] D8 T
EPi 7 0#-d*z D T80#-U !l]h 7K8 T*P4
78 0#-W9}V]9 7D8 TWgj)df :(
E BB6BBBVdW i - , D68A 35#*g j 5 i
!68 0L80#-U !W||i !!LWC5v K8 W !MH; A
qaw-K) XOKWw-K]9 7E8 TW6I>]
9!D8 TWJ-fi 98 (YWxyJ5 EK6’J,! BA7 YWu4]9 7A8 TWui89 !8 Z
KD8 +0MMl$ :@H;= })ZAL*#1 P#5)BA DuYB8?#,([79D uYBvlQC\D|*YB
|}AB*xJ5C"I}n/H=})sC5&
r+iM_BwcfNz_iKr !88 $*n~B0
x! 888 0L5?!wv*< K88 0L?!E*E?j
?! K ’M!Cg{8>_*mEW?-Z) 7K ’M
_ !!LM_5I|T|}uYCDMI|M_i
CD~zS :@FGAqaXYi) NIJOP*Q+REE868 0 S 7D8!0 S
867D!0d.BDt+ZQi*i] D8 TEPi 7
0#-d*zD T80#-U ! l]h 7K8 T*P4 78 0#-W9
}V]97D8 TWgj)df :(EBB6BBBVdWi-
, D68A 35#*gj5i !68 0L80#-U !W||i !!LW
C5v K8 W !MH;Aqaw-K) XOKWw-K]
97E8 TW6I>]9 !D8 TWJ-fi 98 (YWx
yJ5 EK6TWui89!8 Z KD8 +0MMl$ :@H;= })ZA
L*#1 P#5)BA\DuYB8?#,([79DuYBvlQ
C\D|*YB|}AB*xJ5C"I}n/H
=})sC5&r+iM
" noI)S
,CII|kxBsC(w-5B*#B !M
FGJH;Cw@Ax5,CII|kxBsC*#9
!M19 ! 6]*Kg FGJH; -g\]rM_i|
}Cw~A*Cwx DEO}1i*#1/H#w+
\]rCw5}1i|}@A*@Ax D8 OsC*
, EOr]iM‘@A5}1i@(!xeC5
BKVzo*@XY(!xJ5C5 B96K<9VM!7%
z5,CII|kxi5nFeC)%0UV*&
r+i) !<6DA!V*\p)HUQWE =*&r+i
) !D68KDVM
S>@A5}1iv*E8#UZE8#U%;E8*+E8Q:E8PITE*
&r+i) 9699KVW[5D, !< O*)"U G,
E8>K9! & ’ ( ) KD"


}1i!!ZE8"!ZE8]E8"!E,Ee!v
wl"~I(3’_,lz|})c)RF5j!
iuES/He*"##$WWEe*"##%W?3*"##"W?
s[e*"##&dMSBa%IAP<=B*,CIk563xh*0A,\O95q4M,CI[5Dkxi(5+i;\O9sC5esvN*
r,CI\k5})Hu,\|5vw*1(Fl
$*’JhP;XYf5~Ae|Is%EMm
,*,CII|kxisC;+iS‘J^#K2
3}*D,4|IsGHM
E F - .
x11*xbh*’8b*e ’ ()$* ’ Az,CI8xvII|T5
})sC ’ ,C_iGH*)E+da,#, ! ,#$’
COf*) O*i e*e ’ ())% ’ _ikxBphiuS3’>
^v5AgA5g-; ’ _P\]A?.*(%E,da&* ! &)’
WiJ*|/4*[G(*e ’ ()), ’ TI|WWTDEes5GH
E#d999DE+iAn~8Wy;R<5Oc ’ FG&’H)
)H*(*E+&da,# ! ,,’
S/H*4ht*t : ’ "##$ ’ z,_WI $:YckxB}1i
5vFCD ’ &’()*++E%da)( ! )%’
W E*c>\*mKg*e ’ "##% ’ ‘J63LABUnDEkx
i+i53};I#RQr\eC5WRJyf5 ’ *’)
H*+)E"da(*) ! ($$’
tzq*io#*i>{ ’ "##+ ’ ,CI\k562BCD ’ vX3
&W’*"&E+da&# ! &"’
lBh*[bH*[Mp*e ’ "##+ ’ R[+i}) ’ FGa0.3
hx89 ’
2RR*d|&*m H*e ’ "##" ’ CFoG5\r,CIGM_
zB~z ’ *’]$*&)E,da&$+ ! &$%’
jW%*F/H ’ "##* ’ Hj!:f5_ikxiGH|N ’ ,fa
’)H*()E"da(&, ! (+#’
? 3*WVI*; x ’ "##" ’ ,CIrI5\54jfn;\k
xB}1ies ’ RF&’H)H*&#E+da+* ! +)’
?s[*W,J ’ "##& ’ wpI|Wv5kxiurwpI+’z
|})5vw ’ &’()*&)E%da)( ! )&’
-./0 1 2*3.456/4 7*-89:; <*!" #$ ’ "##+ ’ =40>4?4@6>@. 8? A88: ;./B.>84:C
4> ;D. /.C4C;6>@. 8? =@8;C B4>. B/8E.>6>@.C 6064>C; ;D. 89: D8FC.G8/./*
3H98;/FB.C G65F9FC*6>: G/8A>"/8; ?F>0FC*I8>48BD8/6 BF;.6>6’ 78F/>69
8? ID.J4@69 K@8980H*&#E(da(", ! (+(’
L4CC./ 7 3’ ()$% ’ 38C; 8:8/ B./@.B;48> 4> BDH;8BD608FC 4>C.@;C’ 1>>F69
M.E4.A 8? K>;8J8980H*&(a("( ! (++’
!"#$% g’%(
**(! ,# - jea,CII|5kxB})sC