摘 要 :本文对云南曲靖产大蒜(Allium sativum L.) 蒜油用气相色谱和色谱一质谱法进行了分析,鉴定了20个化合物。其中:6-甲基-1-硫杂-2,4-环己二烯(6-methyl- l-thi-2,4-cyclohexadiene),5-甲基-1,2-二硫杂-3-环戊烯(5-methyl-l,2-dithi-3-cyclopentene),4-甲基-1,2-二硫杂-3-环戊烯(4-methyl-1,2-dithi-3-cyclo-pentene),4-乙烯基-1,2,3-三硫杂-5-环己烯(4-vinyl,2,3-trithi-5-cyclohexene)及甲基烯丙基五硫醚(allyl methyl pentasulfide)等为蒜油中首次报道的化合物。
Abstract:The garlic oil from Allium sativumL. cultivated in Qujing, Yun-nan, China was investigated with GC and GC-MS; 20 compounds were identified and 5 of them never yet reported for the garlic oil, namely, 6-methyl-l-thi-2 ,4 -cyclohcxadien.e, 5 -methyl- 1 , 2 -dithi- 3 -cyclopentene, 4 -methyl- 1 , 2 -dithi -cyclopentene, 4 -vinyl- 1,2,3 -trithi- 5 -cyclohexene and Allyl methyl pentasu-Ifide. The main components are 3-vinyl-1, 2-dithi-5-cyclohexene and 3-vinyl - 1 , 2 -dithi- 4 -cyclohexene.