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The Existence of Isosteroidal Alkaloids in Fritillaria L.(Liliaceae) and Its Taxonomical Significance


 The plant chemotaxonomical marker of Fritillaria L. is discussed in this
paper according to the information on chemical components. Plenty of evidence
shows that 5α-cevanine isosteroidal alkaloids are the characteristic constituents of
this genus. In the light of the biogensis of this kind of alkaloids, the C-13 and
C- 17 of the molecular structures may be rational positions uniting a nitrogenous
group in their biosyntheses which make two kinds of 5α-cevanine isosteroidal
alkaloids,  the  dihydrogen  of C- 13  and  C- 17  being  at  the  state  of
trans-configuration (e. g. verticine, verticinone) and at the state of cis-
configuration (e.g. delavine, chuanbeinone and songbeinine). Meanwhile, this
paper reports the existence and content of some 5α-cevanine isosteroidal alkaloids
in main Chinese fritillarias.  This result reveals that there may be a relationship
between the formation of characteristic constituents on one hand and other
morphological characters and distribution of the plants concerned on the other,
which encourages further investigation.


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