免费文献传递   相关文献

Fast analytical method on content and transfer rate of marker component in ethanol precipitation of cinobufacini by near infrared spectroscopy

一种基于近红外光谱的华蟾素醇沉过程指标成分及其转移率快速测定方法



全 文 :#vwtxv
#
| s”c®Id[Îe—fg¡h!À
Ú6GªK^ijL%ԅ”
Ý}
#
~
#
<%€
#
¼‚
!
!
aœB¯ ,Ï9LMNO
#
aœ -W
OPMMLN
$
„;
%!

&
£¤| jL%ÔÎe—fg¡hrlm¨ãÌ`Z·ÑK^i[”c®Id”

†‡
.
H®Îe—f
g¡hþ
!
c®6II”êA“6‹…”%Ԑþrlm¨ãÌ`<
!
Ë¡Eːþ[ni
#
IdžÖ¥ÑnP´
µ
!
o›B/6üp”
$8B1%
£¤”c®Idilm¨ãÌ`<6‹_gš™8Ü»²â
!
>Afg¡h[A퐤öÉ
Z·ÑK^iž%

ˆ‰
.
Ü»²â[j‰F(k(
Mg_XP O!3<1-!3<1-8

MgP[W!MgPX_!
.P²â[
38R
ê
^gPO!
h.j²â*öÉÔ·6‹

ˆŠ
.
]rÇfg¡hr”c®Id”*Eê| jL
#
+/
#
,Ð[Ù%…”q\›

$
‹Œ
%!
”c®Id”
&
fg¡h
&

&
K^i
&
B/6üp”
&
¡h6‹
$
8Ž$f
%!WMPPMOPWMML
$
Ep
%!
Q]Riqö÷«u
$WMMNMOMML%
$
‘‚>’
%!
!
BÀF
!
ƒ„¯
!@(&.$ML[P%NNWMNXWP!-;I$&.&4K;
4(0/)*\aH4g(54gG)
$
>’“”
%!
hr
!
¤7ƒ„ã
!
‚&±×¡h6‹…†ƒ„
!
-;I$&.V/$&$PWOP\PXOgG/I
!!
eK?esöÊÌrÎqes
:,84E,84<+<+B
)*+./
[»tK
P(
!
Îe—êeKµ#Ì
!
wè“z

#
“aÂ
#
,Pu0
#
vܝžãx
#
¿Æ¹ã
‡Þé
W;O(

ªÚ6j£
!
wþSžÚ6w«MA
Ô,
!
vh‚&%ÔÎe—r5lm¨ãÌ`[Z
·;ZÜY·
P(

]Îe—p\NÞr
!
fgªíEyH
#
Ö¥
·q>*èé(iëӛ£Y[C-
^;X(
!
Úê9
Ü¡hr‰ŠH8íEg|

Ÿg§7x%fg¡
h!ÀÚ6Z·D!
AAÆÃ5šEԛ?)ê
i&[

Z7
!
K^i?fg¡hi&[{|!À
!
gû¨á¢fg[öÉh


!
ƒ„gœ§R
!ÀÚ6Z·ÑK^i[§7x%…”
!
VêrÇ
fg9Ü¡h[Y·ZÜÑ]nÙ%µo÷Ñ
Ýì

!ã[Îe—6‹…”èýéßj{d”
[(
#
c®6II”
P(
‡
!
|}…”[þžÖ¥j
£
#
6‹7šx
#
Aþèyz›
!
Y¬§7á¢
þëìÑq÷jL6‹

”c®Id”
$)($%
)6%$%(5 0U(G2%/0G/UA!>:31%
;¬è¼Ì6¥r
;.!>;.!T;.
‡Z{sy[ý|iÄ|ËÊ
N(
!
L
ªw诛EÔ
#
6‹Lj
#
þYמ֥
#
Aþ,}Ÿ,yz‡¯-
!
Ï˘61\›]r
Çãä[µ#
#

#
q¨‘ýp\‡™H8íE
r
_;PW(

¤ƒ„Îe—fg¡hêAx
!
”c
®Idê÷ÑhP
!
0Ä\].·]…”
!
£¤%Ô
fg¡hrlm¨ãÌ`Z·ÑK^i[jL
#
+
/
#
ýé[6‹…”

!
ÁÂi…”
!_!
ßàiçÛ
=)2$%0
#~¤‹DO”c®Idß
$

@#(%I/>G/&(2
–$
%!
q´#
.
ßþgÞÙ%à
!W
II
~.LŽ${»
&@PNMP
c®6II.
$
øù
N‹m›ßàè#kl–$
%&99;P
­N.Ê€à
$
tS‚ƒ>.àè#–$
%&J=WMM^
.¥8ì
$
_&„ìö]ßàè#–$
!
9
MgP I*%&@.R;
MXd
FGÂG…
$
0n8Âßàå
%&
†Êl
$

^ÅÂolè#–$
%
Îe—<¢ß
$

%&L;
‡{ˆA“þ
$
Ãf
NMO;_WMW!
r­ÇþãÌÜþÙÔ²
%&
AütÖs
tr
$
6‹p
%&
ˆ@
$
6‹p
%&_Lh
øf
$
Ǜ
Ý
%&<&U/%(
 pë

!_#
þ[ÜÝ
#Îe—<¢ß
$
˜˜3ê
PgPW */IB
QP
%
P MMM IB!
#ÂGëÑab[‰7r
!
]abG
/_[^W/
{
OX
ï{
PN
•
WMPP
÷
_
²
!!!!!! ! ! ! ! ! !!!! ! ! ! !
S/&gOX! :004(!PN
1(U2(I`(%! WMPP
LM l!
€KL
OMM %/I)
QP
[àqª
!

XM IB/
I)
QP
[oLaÐ
_Lh
øf
O MMM IB!
Í£-øf

[Mh
ò^

êH®Wœ[þ
!
fg¡h
ìÉöÉ
L
5

75fg¡h±{
WM
65—˜#

$
h
WM I)
þFêyë[QŠß
!
#-C&q
!
bƒY(
%!
ê)fgD\LiÚ[#7š-
.
{
WM oWL
65šœ
P I)

!
{
WX oO^
65šœ
W
I)

!
¾
PX I)
šœ
^ I)


h
^
5Ð#
LL
þÙÚÜ»®›£¤Ü»²â
!
{
L
Ã#
PX
þEê¨Æ®›¨Æ²â[ž%›g

!_$
ãÌ`Z·ÑK^i[%Ô
²&þ#
P IB
‹Sæj\ý(
!

L;
‡{ˆ
EA“
!

PLh
AütÖstrˆ@u{ÛÓ
ß
!
“6II”
!
]
LLL )I
[nxÖ%Ԑþr
lm¨ãÌ`[Y·<
P(

Ü»®Ñ¨Æ®[
þZ·ncB¼
P
¼
P!
þrlm¨ãÌ`[Y·*/B
QP
¤ /6_ /q_ Œ_
Ü»®
MgLN ^gPL Pg_^
¨Æ®
PgWO Og_L WgOW
ê)þrY·!
K^i
.P–}ê
$
Y
3
!
/T
!
3
M
/T
M
$P%
}r
!
$êK^i
!3
M
êfgÇߘ˜<
!T
M
êfgÇߘ˜þU
!3
!
ê
!
7ŒfgÇß<
!T
!
ê
!
7ŒfgÇßþU

!_%
”c®Id6‹
ŽÎe—fg¡hþ[gÞId
!
Id
Ž2
^ MMM oPM MMM GI
QP
!
Ž5(
OW
5
!
6i
N GI
QP
!
§¨¯›coê$öÉId¯®
$
G
WL l!

^Mh%
!_&
Id()Ö¥…”i²â›g{|!À

@#(%I/>G/&(2
–$
TI)G
,q[
@d=);
$&A02
Ø6r[B/6üp”
$ U$%2$&&($020]4$%(!
8B1%
£¤þrlm¨ãÌ`[”c®IdÔ·
6‹²â

²â£¤hAÜ»®IdöÉEË-
µý²â9
!
Z7ȘId]ì
#
X6‡‹
Œ[IdžÖ¥…”ª“ißàÅçJ‘^Anf
[WX
!
´µÄ‹[nPµ#èénc
!
áe.P
·
!
¢’£²7š

¤§¨m¡“|”’>¨Æ
!
’>¨Æ-C
Œ…ê
$%//2I($) 0]4$%((%/%/6G%/00D$&5$2/)!
3<1-S%
ê!À/Ô/‹‚b¥(

A£¤[
>:31;8B1
Ô·²â
!
j‰F(
2
W
!
Ü»®ž%-
CŒ…ê
$%//2I($) 0]4$%((%/%/6G$&`%$2/)!3<;
1-%
ѨƮž%-CŒ…ê
$%//2I($) 0]4$%(
(%/%/6U%(5G2/)!3<1-8%
‘¿²â›g

ÿ®
!
¬
›Ü»®[jA6‹-C
$%(054$&U%(5G2D(5(D$;
2/)!38R%
_AÔ·²â[ž%9³ö|N¨
Æ
PO(

|ŸZ´ª
!

38R

L
7(ê?²
âž%gN?_&nl[
!38R
]
WgL oL
7(ê
²âöÉÔ·6‹?*É[
!
ìž%9è͝i
ö|Nµý
!38R

WgL
h.²â]Ô·7Œ]
|Ԕ•

#
0•i†,
#_!
”c®IdÔ·²â[˜N£¤
#_!_!
Eːþ[ni
!
]£²¡hr
!
Id²â
äª(_™b—[WX
!
û*b[¾D
#
ßà[-
C
#
íE[-C
#
¤žÖ¥Y·
!
|}ÈbDä
‚°Eːþ[äã

Eːþ
$/42&(%%
[Œ]2
iWX²â[‹››Ñ+/›
!
‘–Vª±Ü»
®rni

¤5§¨r
!
6¯›þ[—˜_
$&(D(%$*(%
Ñ]ã\™C
$0245()2a(5 %(054$&%

Eːþ
P^(

þ—˜_¼½þA²âWX[i&h
!
mËI˜%Ù6<Œ_֐þ[—˜_&6
!
Ÿ þ[—˜_Xqª{_
!
Š*g?Id
ŽJª{6‹…”%Ô7“Ð-C‚°Ygô¼
þ[§1Z´

]ã\™C_¼½iþ_A[þ<ž%gN[‰z
!
Ÿ|þè&ý[
™C_
!
š›h.ƒþ[6‹(°>0è]Ü»
®…”£¤[²â~

þ
P
è&ý[]ã\™C
_
!
þ
W
Ñ
O
è&ý[—˜_
!
bƒEêEË-n
i
!
Bd
P
#_!_#
IdžÖ¥
!
L*b[WX
!>:3
Id%
ÔrŒ]YEԛ
!
²]öɔc®Id6‹g
h|Ÿ×&A¯®([ȘIdöɑ&[ìÑ
‚‡(]žÖ¥

AȘId6öɏ|OX
6
#
üOX6
#1$D20VA;?/&$A
únì
$1;?%#>/%0
‚(ún쐇
!
A$ƒ„¿ IdžÖ¥…”
A²&²â
2
W
Ñ
3<1-S
[WX
!

W
/MN^W/
{
OX
ï{
PN
•
WMPP
÷
_
²
!!!!!! ! ! ! ! ! !!!! ! ! ! !
S/&gOX! :004(!PN
1(U2(I`(%! WMPP
dP!
¤À+—˜_i]ã™C[j‰‰Fd
¼
W!
YZIdžÖ¥…”A
8B1
²âž%0•[WX
žÖ¥…”
3<1-S
2
W
J=@T31
ȘId
MgW_ MgNNX P L
,X6
m1;? MgW_ MgNNX P L
|OX6
m1;? MgOW MgNXO P ^
|OX6
m>/%0 MgWW Mg_ON P _
üOX6
m1;? MgOL MgNWL M W
üOX6
m>/%0 MgWL Mg_P[ M X
m¡$&*R
!
ȘIdöÉ
>/%0
‚(ún
ìÖ¥¾
!
|OX6ÑüOX6&([²âDè
jA&F[
3<1-S
§
2
W
k(
Mg_
_

|OX
6gœ.u“iId[snì^
!
üOX6*“
iId[sn—K

Lfg¡høfYaÐ
!
ȘIdKR.u[snì^
!
²AȘIdö
É|OX6Ñ
>/%0
‚(únìÖ¥
!
&([²
â›g/…

#_!_$
nP´µ
!
êé²â£¤rœ_Ö¥Od
nc
!
ìL”c®Id()mˌ]2i[nX
iXÑÐn›
!
bƒ×&C\ddnc
!
¢´K¯
Id(°
!
µýoPéiѲâY·

±|OX6IdY•R
!
nP
N [^L oN OM^!
[ ^NO oX WW[!X MWM oL XO^ GI
QP
֐þGH¥Œ
]CE›
!
Bd
W
¯›OnxÑ
N [^L oN OM^!
[ ^NO oX WW[!X MWM oL XO^ GI
QP
GªÙÄnP[I
d()£¤[Ü»²â[
2
W
Ñ
3<1-S

O
$&YZnPId£²[0•
!
¼.Z7´µ
N [^L oN OM^![ ^NO oX WW[!X MWM oL XO^ GI
QP
O

nP£²*&(/ý[
2
W
Ñ/F[
3<1-S
#_!_%
/…‚b¥(/Ô
!
¯›
8B1
”£¤Ô·
Ü»²â7
!
×&A‚b¥(öÉÄ¥´µ

Îb
¥(´#¡67䂰²ânc·Yœ
!
b¥(´
!!
d
W!
|OX6IddÑnP´µ
¼
O!
YZIdnP´µA
8B1
²âž%gN[WX
>/g
nP
ZGI
QP
3<1-S
2
W
P PM MMM o^ MMM MgO[ MgNMP N
W N [^L oN OM^ MgOP MgN[M P
O [ ^NO oX WW[ MgOP MgNXX M
^ X MWM oL XO^ MgWO Mg_WN W
L N [^L oN OM^![ ^NO oX WW[ MgWO Mg_O^ ^
X MWM oL XO^
#¡q74ãÚ²â[
)
¡þÄ
*
Rx[äã
!
b
ƒ´µ›Ô·6‹›[/…b¥(AAÆÔ·²
âž%Eԛ‰Ëi&

]
N [^L oN OM^![ ^NO oX
WW[!X MWM oL XO^ GI
QP
ª
!
¯›“|’¾¨Æ”
!
‘
¿‚b¥(A~ؒ¾¨ÆŒ…C
$3<1-S%
[
WX
!
Bd
O
΂b¥(ê
X
7
3<1-S
/6
!
b
ƒ/Ô/…‚b¥(ê
X!
ƒ7
3<1-S
ê
MgWO
d
O!
/…‚b¥(ђ¾¨Æç¨
#_!_&
”c®Ô·²â[£¤
!
Ë¡Eːþ[
ni
#
IdžÖ¥ÑnP´µ
!
V{
P!W!O!^
Ðþ
EêÜ»®
!
ni
O
Eː¤
!
¯›|OX6Ñ
/PN^W/
{
OX
ï{
PN
•
WMPP
÷
_
²
!!!!!! ! ! ! ! ! !!!! ! ! ! !
S/&gOX! :004(!PN
1(U2(I`(%! WMPP
>/%0
‚(únìÖ¥
!
]
N [^L oN OM^![ ^NO o
X WW[!X MWM oL XO^ GI
QP
nP~\›
8B1
£¤Îe
—fg¡hrlm¨ãÌ`Ô·Ü»²â
!
ªr‚
b¥(ê
X
Ü»®þ
,S
§%_i
>:3
ž%_
[j‰‰FdBd
^
dr²½
>:3
ž%_0”§
%_
!
Ü»²â[
2
W
k(
Mg_XP O!3<1-
ê
MgP[W!3<1-8
Šê
MgPX_!
’>¨Ær
3<1-S
ê
MgWO
.PÜ»®[
38R
ê
^gPO!38R
]
WgL oL
7(ê²âöÉÔ·6‹?*É[

d
^!
Ü»®Ñ¨Æ®þž%_i§%_[j‰‰Fd
#_#
Îe—fg¡h[ž%
V£¤[Ô·²âA{
L
稲&þöÉ
Îe—fg¡hZ·ž%
!
Z7’“–}
$P%
.P
K^i
!
Bd
L
²âž%fg¡hlm¨ãÌ`
Z·ÑK^iD\ܚi§%“ns¤Aì|°
!
h.²£¤[”c®Id”?*É[

Z·D\“
n*á¢fg¡h[Eԛ
!
ŸÃ5šZ·“n
jC&q
!
Šh.LíE-CJ*bb—‚°
Ã5š[CE›
&
K^iD\“n*ž!ÀÚ
6[K^h
!
Îk(
NMh oNLh
7
!
h.]jN
ÞàqªqØ6lm¨ãÌ`ӝøfi£Y&
6e
!
Îe—fg¡hs¤0À

|A]§1ãä
r£¤¡h6‹…”
#
xŸNÞEԛ
#
fg£
-èk!‚›[@›

$
0,
¤ƒ„£¤Îe—fg¡h”c®IdjL6
‹…”
!
£¤[”c®Ü»²â
2
W
ê
Mg_XP O!
38R
ê
^gPO!
ÓWÔ·ž%[×&
&
i!ã6‹…
”j$
!
¯›”c®Id”%Ô6‹éiý
!
h.”
c®Id”*Eê| jL[Ô·6‹…”›
%ÔÎe—fg¡h

Z7
!
¯›lm¨ãÌ`
!!
d
L!
fg¡hZ·
$=%
ÑK^i
$7%
§%_
ў%_!7š[DZ·ÑK^i
W
 !ÀOT‘¿fghÑäþY
·
!
|AN=\ãäwè!‚›@›

è Vƒ…
”æ6(ª{rÇþ 
!
êrÇÜÇ[fg¡hY
·ZÜÑ]nÙ%µoŠ[÷ÑÝì

$
•–—˜
%
P (!
rαÏÐÑ­Ø¡ÇþÀ+
g
Îe—?ÞßÙ¨…”
1(F
øù
.
r­À+K±
! P__[.PXg
W (!
“z´
g
Îe—?ÞßÇ¥ƒ„iåæ\›
9(g
7¢­î
­Ç
! P___! PM $L%.Pg
O (!
£¤¥
!

!
§Ã¨
!
‡
g
Îe—?Þß·Ä\òSž
åæ\›ƒ„ö÷
9(g
ÚÛîÇ
! WMPM! P^$P%.Og
^ (!
Ba
!
¢Ú
!
¹´
!
‡
g
rÇfgNÞGáÝù‹
9(g
r
ÚÇ
! WMM[! W_$N%.Og
L (!
ôü
!
©ìª
g
rÇfgNÞ[‰ŠWXb—
9(g
rÚÇ
!
WMML! W[$W%.Wg
X (!

!
¬­®
!
¾¯
!
‡
g
ëµfg”rfg±²rÜÝ¡h[WX
9(g
r­rÇ£¤
! WMPM! OL$O%.
WNNg
[ (!
¹c³
!
ñ
!
¹´
!
‡
g.8B
”%ÔÎe—?ÞßrÎ
e—Z·Gè‰ÌY
9(g
~µî]
! WMMN! P_$N%.Wg
N (!
¶6m
!
·­5
!
¸¹¢
!
‡
g
Rô”c®Id÷ÑG\›
ö÷
9(g
Id]iId6‹
! WMMM! WM$W%._g
_ (!
LJ
!
ºâ’
!
ì»
!
‡
g
”c®Id”Ô·6‹ÇA“
꼐µ#ßr‚&Ú6
9(g
r­rÇ£¤
! WMMN! OO
$P[%.Wg
PM(!
NÀŽ
!
Ãqƒ
!

!
‡
g
c_ãoµ#¡h”c®Id
jL%ԅ”ƒ„
9(g
6‹\]
! WMM_! O[$PM%.P^LPg
PP(!
¾&¿
!
ÿ
!
BÀF
!
‡
g
cfµß<¢¡h”c®I
d]n6‹…”
9(g
r­Ç]£¤
! WMML! ^M$W^%.^g
PW(!
ìý’
!
hÀÁ
!
¾&¿
!
‡
g
| ›rÇp\¡h[”
c®Id6‹Š…”
9(g
\]]1
! WMMO! XP$L%.X
/WN^W/
{
OX
ï{
PN
•
WMPP
÷
_
²
!!!!!! ! ! ! ! ! !!!! ! ! ! !
S/&gOX! :004(!PN
1(U2(I`(%! WMPP
PO(!<$&(ARJ!J)5&$ARB!eUU(:7!(2$&gJ($0`&2A/640)*
)($%;)6%$%(5 %(6&(G2$)G(0U(G2%/0G/UA6/%2#($)$&A00/6>8$)5
5/$2/I0) &$V(0(5I()209(g98$&(/&I)/&! P___! WP $L%.
W_Lg
P^(!//V 3Rg3(054$&0$)5 )6&4()G() %(*%(00/)g#$U2(%
#
<(g>(Ec/%V. #$UI$) $)5 .$&! P_NWg
UB.LBCACD0CADE/CB1LGAU0L0D/D0BCBNU0CBMIN/U0C0
MF CA/G0CNG/GAHKLAUDGBKUBLF
1,>R! c,=>9$! .,+$/A$)! B:,+4(0/)*
!
$M./!)!,!-48>45-. 3().-/->-5)&).-! K(-;)+.< =.)6-/)!%! H+.<*(4, OPMMLN! 3().+%
6MKDG/UD(!@#(I(2#/5 /6)($%)6%$%(5 0U(G2%/0G/UAE$0(02$`&0#(5 2/$)$&Aa(2#(G/)2()2$)5 2%$)06(%%$2(/62#(I$%V(%G/I;
U/)()2! )5/&($&V$&/50! /6G)/`46$G)) 2#(U%/G(00/6(2#$)/&U%(GU2$2/)g@#(0$IU&(0/6G)/`46$G)E(%(G/&(G2(5! $)5 2#(
G/)G()2%$2/) /6)5/&($&V$&/50E$05(2(%I)(5 `A2#(%(6(%()G(I(2#/5! ,S;D00U(G2%/0G/UAg=62(%2#(%(H(G2/) /6$`)/%I$&0$I;
U&(0! 2#(U%(2%($2I()2/60U(G2%$$)5 2#(G#/G(/62#(G/%(0U/)5)*E$D(` $)5! 2#(I4&2D$%$2(G$&`%$2/) I/5(&0E(%((02$`&0#(5
40)*8B1 $&*/%2#I`(2E(() 0U(G2%$$)5 2#(,SD$&4(0g@#(0$IU&(0) (2#$)/&U%(GU2$2/)! E#G# 55 )/2U$%2GU$2() I/5(&)*!
E(%(40(5 2/(K$I)(2#(U(%6/%I$)G(/62#(I/5(&0g@#(G/%(&$2/) G/(6G()2/62#(G$&`%$2/) I/5(&E$0Mg_XP Og3//2I($)
0]4$%((%/%/6G$&`%$2/) $3<1-% $)5 %//2I($) 0]4$%((%/%/6U%(5G2/) $3<1-8% E(%(MgP[W $)5 MgPX_! %(0U(G2D(&AgJ4%;
2#(%I/%(! %(054$&U%(5G2D(5(D$2/) $38R% /62#(I/5(&E$0^gPO! E#G# I($)2]4$)22A$)$&A00E$06($0`&(g:20G/)G&45(5 2#$2
)($%)6%$%(5 0U(G2%/0G/UAG$) `(G/)05(%(5 $0$6$02! (6(G2D($)5 )/);5(02%4G2D($)$&A00I(2#/5 $UU&(5 ) 2#(U%/G(00/6(2#$)/&
U%(GU2$2/) 6/%2%$52/)$&#)(0(I(5G)(g
A^F YBGHK(!)($%)6%$%(5 0U(G2%/0G/UA& (2#$)/&U%(GU2$2/)& G/)2()2& 2%$)06(%%$2(& U$%2$&&($020]4$%(I(2#/5& U%/G(00
$)$&A00g
HB0.!+ %`#)QU]U..#+!!!)+
$
™š$Q
!
Ÿ ¡
%
/ON^W/
{
OX
ï{
PN
•
WMPP
÷
_
²
!!!!!! ! ! ! ! ! !!!! ! ! ! !
S/&gOX! :004(!PN
1(U2(I`(%! WMPP