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Development of FTIR fingerprint for identification of armand clematis stem (Chuanmutong) and related herbs

川木通红外光谱指纹图谱的建立及其与相近中药的鉴别



全 文 :2016
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Vol41,No.8 April,2016
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DevelopmentofFTIRfingerprintforidentificationofarmandclematisstem
(Chuanmutong)andrelatedherbs
GAOShanshan1,LIJianrui1,2,WUFangbin1,WEIXuemin1,BIANJinhui1,CHENJianbo4,
CHENGShiqiong3,SUNSuqin4,LVGuanghua1
(1KeyLaboratoryofEducationMinistryinChinaforStandardizationofChineseMateriaMedica,Schoolof
Pharmacy,ChengduUniversityofTraditionalChineseMedicine,Chengdu611137,China;
2PerkinElmerInstruments(Shanghai)Co,Ltd,Chengdu610016,China;
3SichuanProvincialInstituteforFoodandDrugControl,Chengdu610097,China;
4DepartmentofChemistry,TsinghuaUniversity,Beijing100084,China)
[Abstract] Armandclematisstem(ClematidisArmandiCaulis,Chuanmutong)isawidelyusedChineseherbtodisinhibiturine
andrelievestranguriaItisdificulttobeidentifiedowingtoitsvariousmacroscopicfeatureandunknowncharacteristiccompounds
·5841·
2016
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Vol41,No.8 April,2016
Thus,totalof24Chuanmutongsamplesand7relatedherbsincludingfourmanshurianaristolochiastem(AristolochiaeManshuriensis
Caulis,Guanmutong)andthreeakebiastem(AkebiaeCaulis,Mutong)sampleswerecolectedandanalyzedintherangeof4000
400cm-1byFourierTransformInfrared(FTIR)andtwodimensionalinfraredcorelationspectroscopy(2DFTIR)techniquesThe
FTIRspectraof24Chuanmutongsamplesareconsistentinthespectrumprofiles,positionandintensityofcharacteristicpeaks20of
the24ChuanmutongsampleswererandomlyselectedascalibrationsamplestocalculateandsimulatemeanspectrumThismeanspec
trumisnamedasFTIRfingerprintofChuanmutongwithcharacteristicpeaksat3412,2932,1739,1639,1509,1456,1426,
1376,1332,1261,1159,1035,897,609cm-1Meanwhile,thelimitedlevel(Mean-3σ=09926)toidentifytrueorfalse
ChuanmutongbycorelationcoeficientofFTIRspectrawascalculatedbasedonthe20ChuanmutongcalibrationsamplesThen,the
rest4Chuanmutong,4Guanmutongand3MutongsampleswereusedasvalidationsamplestoevaluatetheidentificationeficacyThe
resultshowsthattheFTIRspectraof4ChuanmutongvalidationsamplesweresimilartothefingerprintTheircorelationcoeficientsof
FTIRspectrawereoverthelimitedlevelandacceptedasChuanmutongHowever,thespectraofGuanmutongandMutongweresignifi
cantlydiferentfromChuanmutongfingerprintThecorelationcoeficientsofGuanmutong(0902109404,n=4)andMutong
(0954909789,n=3)FTIRspectrawerelessthanthelimitedlevelandrejectedfromChuanmutongFurthermore,thenumber,
positionandintensityofautopeaksonthe2DFTIRweredrasticalydiferentamongthethreeherbsItisconcludedthatthedeveloped
FTIRfingerprintingcanberapidlyandaccuratelyidentifyChuanmutonganddiferentiatefromrelatedherbs
[Keywords] ClematidisArmandiCaulis;manshurianaristolochiastem;akebiastem;Fouriertransforminfrared;fingerprint;cor
relationcoeficient;identification
doi:10.4268/cjcmm20160820
  
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·7841·
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Vol41,No.8 April,2016
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