免费文献传递   相关文献

Studies on xanthones from aerial parts of Polygala sibirica

卵叶远志地上部分酮类成分研究


目的:系统研究卵叶远志Polygala sibirica地上部分的化学成分。方法:采用各种柱色谱方法进行分离,利用波谱数据鉴定化合物的结构。结果:分离、鉴定了10个化合物,其中6个为酮类化合物,分别为6 羟基 1,2,3,7 四甲氧基酮(1);1,2,3,6,7 五甲氧基酮(2);1,7 二羟基 2,3 亚甲二氧基酮(3);1,7 二羟基 2,3 二甲氧基酮(4);1,3,7 三羟基 2 甲氧基酮(5);1,6,7 三羟基 2,3 二甲氧基酮(6)。此外还分离得到α 菠甾醇(7);α 菠甾醇 3 O β D 葡萄糖苷(8);角鲨烯(9)和远志糖醇(10)。结论:化合物1~10均为首次从本植物中分离得到。

Objective: To investigate the chemical constituents of the aerial parts of Polygala sibirica systematically.  Method: The chemical constituents were isolated by various column chromatographic methods. The structures were identified by spectral data.  Result: Ten compounds were isolated and identified as 6 hydroxy 1, 2, 3, 7 tetramethoxy xanthone (1); 1, 2, 3, 6, 7 heptamethoxy xanthone (2); 1, 7 didydroxy 2, 3 methylenedioxy xanthone (3); 1, 7 dihydroxy 2, 3 dimethoxy xanthone (4); 1, 3, 7 trihydroxy 2 methoxy xanthone (5); 1, 6, 7 trihydroxy 2, 3 dimethoxy xanthone (6); α spinasterol (7); α spinasterolic 3 O β D glucoside (8); squalene (9) and polygital (10).  Conclusion: Compounds 1 10 were isolated from this species for the first time.